Sains Malaysiana 53(10)(2024): 3279-3288

http://doi.org/10.17576/jsm-2024-5310-04

 

Komposisi Isotop Radiogenik Pb Longgokan Emas Orogeni Bufffalo Reef, Pahang, Malaysia: Implikasi terhadap Genesis Bijih

(Radiogenic Pb Isotope Composition of the Buffalo Reef Orogenic Gold Deposit, Pahang, Malaysia: Implications for Ore Genesis)

MAZLINFALINA MOHD ZIN1,*, MOHD BASRIL ISWADI BASORI1, HABIBAH JAMIL1 & NASIRUDIN YUSOFF2

 

1Jabatan Sains Bumi dan Alam Sekitar, Fakulti Sains dan Teknologi, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan, Malaysia

2Pejabat Dekan, Fakulti Sains dan Teknologi, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia

 

Received: 19 May 2024/Diterima: 11 Accepted 2024

 

Abstrak

Longgokan emas Buffalo Reef di Jalur Tengah Semenanjung Malaysia merupakan longgokan jenis orogeni yang berkongsi banyak cirian geologi dengan longgokan emas orogeni lain di rantau ini. Batuan perumah di Buffalo Reef didominasi oleh batuan sedimen iaitu syal, syal berkarbon, batu lodak, batu lumpur, batuan metamorf gred rendah (sabak) dan batuan volkanik.   Komposisi isotop Pb bagi sulfida di dalam telerang kuarza dan batuan perumah daripada longgokan emas Buffalo Reef dilaporkan dalam kajian ini sebagai salah satu kaedah untuk menentukan sumber larutan pembentuk bijih, julat sempadan usia (modal age) dan sekitaran tektonik. Hasil kajian ini kemudiannya disepadukan dengan gambaran keseluruhan sekitaran geodinamik serantau, untuk lebih memahami tentang genesis longgokan emas orogeni di rantau ini. Empat mineral stibnit di dalam telerang kuarza memberikan julat nisbah 206Pb/204Pb daripada 18.5953 hingga 18.6318, nisbah 207Pb/204Pb antara 15.6564 dan 15.6910 dan nisbah 208Pb/204Pb sekitar 38.6378 hingga 38.7503. Sementara itu, nisbah untuk 206Pb/204Pb, 207Pb/204Pb dan 208Pb/204Pb bagi satu mineral stibnit daripada batuan perumah ialah 18.6215, 15.6242 dan 38.6132. Secara keseluruhannya, nilai data isotop Pb yang terkandung oleh mineral stibnit di dalam telerang kuarza adalah agak kecil dan menunjukkan persamaan dengan nilai isotop Pb yang terkandung oleh mineral stibnit di dalam batuan perumah. Hasil kajian menunjukkan bahawa sumber utama Pb dalam larutan hidroterma pemineralan di Buffalo Reef berasal daripada percampuran Pb kerak atas dengan Pb daripada sumber igneus/mantel yang terbentuk di sekitaran tektonik subduksi-perlanggaran yang membentuk jalur orogeni. Perbandingan data isotop Pb dalam longgokan emas Buffalo Reef dengan beberapa longgokan emas orogeni di Semenanjung Malaysia menunjukkan nilai isotop Pb dan sekitaran tektonik yang konsisten dan seragam serta semuanya berada dalam julat umur modal 0-200 juta tahun. Penemuan ini selaras dengan kejadian longgokan emas orogeni di Buffalo Reef dan longgokan emas orogeni lain di rantau ini yang terbentuk terutamanya di sepanjang sempadan kerak menumpu bagi jalur orogeni perlanggaran.

 

Kata kunci: Buffalo Reef; emas orogeni; genesis; isotop Pb; Semenanjung Malaysia

 

Abstract

The Buffalo Reef gold deposit in the Central Belt of Peninsular Malaysia is an orogenic deposit type that shares many geologic features with other orogenic gold deposits in this region. The host rocks in the Buffalo Reef are dominated by sedimentary rocks, which are shale, carbonaceous shale, siltstone, mudstone, low-grade metamorphic rock (slate), and volcanic rocks. The Pb isotope compositions of sulfides in quartz veins and host rocks from the Buffalo Reef deposit are reported in this study as an attempt to constrain the source of the ore-forming fluids, modal age and tectonic setting. These results are then integrated with an overview of the regional geodynamic setting to advance understanding of the genesis of the orogenic gold deposits in this region. Four stibnite minerals in quartz veins yield 206Pb/204Pb ratios ranging from 18.5953 to 18.6318, 207Pb/204Pb ratios between 15.6564 and 15.6910, and 208Pb/204Pb ratios around 38.6378 to 38.7503. Meanwhile, the 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios for one stibnite mineral from the host rock are 18.6215, 15.6242, and 38.6132, respectively. Overall, the isotopic Pb data values contained by the stibnite mineral in quartz veins are relatively small and exhibit consistency with the isotopic Pb values contained by the stibnite mineral in the host rock. The results suggest that the primary source of Pb in the hydrothermal mineralizing solution at Buffalo Reef originates from the mixing of Pb from the upper crust with Pb from igneous/mantle sources formed in the vicinity of subduction-collision tectonic settings that form orogenic belts. Comparison of Pb isotopic data in the Buffalo Reef deposit with several orogenic gold deposits in Peninsular Malaysia shows a consistent and uniform pattern of Pb isotopic values and tectonic settings, all falling within the modal ages range of 0-200 million years. These findings are consistent with the formation of the orogenic gold deposit at Buffalo Reef and other orogenic gold deposits in the region that form primarily along convergent plate margins of the collisional orogenic belt.

 

Keywords: Buffalo Reef; genesis; Pb isotope; Peninsular Malaysia; orogenic gold

 

REFERENCES

Ariffin, K.S. & Hewson, N.J. 2007. Gold-related sulfide mineralization and ore genesis of the Penjom gold deposit, Pahang, Malaysia. Resource Geology 57(2): 149-169.

Ariffin, K.S. 2012. Mesothermal Lode Gold Deposit Central Belt Peninsular Malaysia. Dlm. Earth Sciences, disunting oleh Imran Ahmad Dar. IntechOpen.

Basori, M.B.I., Khin Zaw, Meffre, S. & Large, R.R. 2016. Geochemistry, geochronology and tectonic setting of early Permian (~290 Ma) volcanic-hosted massive sulphide deposits of the Tasik Chini district, Peninsular Malaysia. International Geology Review 58: 929-948.

Bierlein, F.P., Groves, D.I. & Cawood, P.A. 2009. Metallogeny of accretionary orogens – the connection between lithospheric processes and metal endowment. Ore Geology Reviews 36: 282-292.

Biswajit, M., Kamal, L.P., Pranjit, H. & Sakthi, S.C. 2018. Nature and source of the ore-forming fluids associated with orogenic gold deposits in the Dharwar Craton. Geoscience Frontiers 9(3): 715-726.

Doe, B.R. & Zartman, R.E. 1979. Plumbotectonics, the Phanerozoic. Dlm. Geochemistry of Hydrothermal Ore Deposits, disunting oleh Barnes, H. New York-Chichester-Brisbane-Tokyo: Wiley-Interscience Publications.

Endut, Z., Ng, T.H., Aziz, J.H.A. & Teh, G.H. 2015. Structural analysis and vein episode of the Penjom Gold Deposit, Malaysia: Implications for gold mineralisation and tectonic history in the Central Belt of Malaysia. Ore Geology Reviews 69: 157-173.

Flindell, P. 2003. Avocet Mining – Exploration and Development Across Central and Southeast Asia, Australia Institute of Geoscientists (AIG), Mineral Exploration Discussion Group (SMEDG), 10 Oct, Sydney. hlm. 8.

Frimmel, H.E. 2008. Earth's continental crustal gold endowment. Earth and Planetary Science Letters 267: 45-55.

Galer, S.J.G. 1998. Practical application of lead triple spiking for correction of instrumental mass discrimination. Chemical Geology 157: 255-274.

Goldfarb, R.J., Groves, D.I. & Gardoll, S. 2001. Orogenic gold and geologic time: A global synthesis. Ore Geology Reviews 18(1-2): 1-75.

Goldfarb, R.J., Baker, T., Dube, B., Groves, D.I., Hart, C.J. & Gosselin, P. 2005. Distribution, character and genesis of gold deposits in metamorphic terranes. Dlm. Economic Geology 100th Anniversary Volume, disunting oleh Hedenquist, J.W., Thompson, J.F.H., Goldfarb, R.J. & Richards, J.P. hlm. 407-450.

Groves, D.I., Goldfarb, R.J., Gebre-Mariam, M., Hagemann, S.G. & Robert, F. 1998. Orogenic gold deposits – A proposed classification in the context of their crustal distribution and relationship to other gold deposit types. Ore Geology Reviews 13: 7-27.

Gunn, A.G. 1994. Gold Sub Programme Final Report: Summary, conclusions and recommendations. Geological Survey of Malaysia and British Geological Survey.

Hutchison, C.S. 1975. Ophiolite in Southeast Asia. Geological Society of America Bulletin 86: 797-806.

Jabatan Mineral dan Geosains Malaysia. 2014. Peta Geologi Semenanjung Malaysia Edisi ke-9, skala 1:750 000. 

Makoundi, C., Zaw, K., Large, R.R., Meffe, S., Lai, C.K. & Hoe, T.G. 2014. Geology, geochemistry and metallogenesis of the Selinsing gold deposit, central Malaysia. Gondwana Research 26(1): 241-261.

Metcalfe, I. 2013a. Gondwana dispersion and Asian accretion: Tectonic and palaeogeographic evolution of eastern Tethys. Journal of Asian Earth Sciences 66: 1-33.

Metcalfe, I. 2013b. Tectonic evolution of the Malay Peninsula. Journal of Asian Earth Sciences 76: 195-213.

Metcalfe, I. 2000. The Bentong-Raub suture zone. Journal of Asian Earth Sciences 18: 691-712.

Mohamed, K.R., Joeharry, M.N.A., Leman, M.S. & Ali, C.A. 2016. The Gua Musang Group: A newly proposed stratigraphic unit for the Permo-Triassic sequence of Northern Central Belt, Peninsular Malaysia. Bulletin of the Geological Society of Malaysia 62: 131-142.

Mohd Zin, M. 2023. Genesis Longgokan Emas Buffalo Reef, Pahang, Malaysia. Tesis Sarjana, Universiti Kebangsaan Malaysia. hlm. 130 (tidak diterbitkan).

Ng, S.W.P., Whitehouse, M.J., Searle, M.P., Robb, L.J., Ghani, A.A., Chung, S.L., Oliver, G.J.H., Gardiner, N.J. & Roselee, M.H. 2015. Petrogenesis of Malaysia granitoids in the Southeast Asian tin belt: Part 2. U-Pb zircon geochronology and tectonic model. Geological Society of American Bulletin127(9-10): 1238-1258.

Phillips, G.N. & Powell, R. 2009. Formation of gold deposits: Review and evaluation of the continuum model. Earth-Science Reviews 94: 1-21.

Poulsen, K.H., Robert, F. & Card, K.D. 1992. Transpressive tectonics and the Archean gold deposits of Superior Province, Canadian Shield. Dlm. Basement Tectonics 8. Proceedings of the International Conferences on Basement Tectonics, vol 2., disunting oleh Bartholomew, M.J., Hyndman, D.W., Mogk, D.W. & Mason, R. Dordrecht: Springer.

Powell, R., Woodhead, J. & Hergt, J. 1998. Uncertainties on lead isotope analyses: Deconvolution in the double-spike method. Chemical Geology 148: 95-104.

Stacy, J.S. & Kramers, J.D. 1975. Approximation of terrestrial lead isotope evolution by a two stage model. Earth and Planetary Science Letters 26: 207-221.

Thirwall, M.F. 2000. Inter-laboratory and other errors in Pb isotopes analyses investigated using a 207Pb-204Pb double spike. Chemical Geology 163: 299-322. 

Tjia, H.D. 1989. The Bentong Suture. Proceedings of the Regional Conference on Mineral and Hydrocarbon Resources of SE Asia. hlm. 73-85.

Wan Fuad Wan Hassan & Heru Sigit Purwanto. 2002. Type deposits of primary gold mineralisation in the Central Belt of Peninsular Malaysia. Geological Society of Malaysia Annual Geological Conference. hlm. 111-116.

Yin, E.H. 1965. Provisional Draft Report on the Geology and Mineral Resources of the Gua Musang Area, Sheet 45, South Kelantan. Geological Survey of Malaysia. hlm. 49 (unpublished).

Yusoff, A.F., Abdul Aziz, J.H. & Roselee, M.H. 2022. Mineralogy and geochemistry of gold mineralization at southern part of Ulu Sokor gold deposit, Kelantan, Malaysia. Sains Malaysiana 51(12): 3865-3877.

Zartman, R.E. & Doe, B.R. 1981. Plumbotectonics-The model. Tectonophysics 75: 135-162.

Zhu, B. 1998. The theory and application of the isotopic systematic in geoscience concurrent discussion of the continental crust and mantle evolvement in China. Beijing: Science Publishing House. hlm. 1-330 (in Chinese).

 

*Corresponding author; email: farlinnzin@gmail.com

 

 

 

 

 

 

 

previous next